Hi Wiebe,
I wouldn't use random numbers, but work with primes below 20. So,
always starting with 1, and then increasing with the prime number
until you reach 100.
You have the following prime numbers : 19,17,13,11,7
Time slot 1 :
group A : 1, 20, 39, 58, 77, 96, (1)15, 34, 53, 72,...
group B : starting with the lowest available number.
group C : starting with the lowest available number.
...
Time slot 2 :
group A : 1, 18, 35, 52, 69, 86, (10)3, 20, 37, 54, 71, 88, (10)5, ...
group B :starting with the lowest available number.
group C : starting with the lowest available number.
...
Time slot 3 : same, but with an increment of 13
Time slot 4 : same, but with an increment of 11
Time slot 5 : same, but with an increment of 7
It might be even more unique when you use even higher primes, but I
guess this methodogy will be fair enough.
It's up to you to write the formulas 
Good luck!
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