Configuring default printing settings possible?

Hello,

Is there some way to set LibreOffice's default printing behaviour for all documents, and to stick to those defaults unless I override them at print time?

Whenever I press print, I want LibreOffice to default to printer #2, two-sided printing, on paper tray #2. I cannot seem to find where to set this in the options.

It seems that LibreOffice is either using random defaults, or saving them on a per-document basis, or using the first available option in the list of parameters (i.e., printer #1, one-sided printing, first paper tray -- all the first items in the respective parameters).

LiberOffice definitely does not respect the default printing options I set in the OS.

Version: 6.4.6.2
Build ID: 1:6.4.6-0ubuntu0.20.04.1
CPU threads: 4; OS: Linux 5.8; UI render: default; VCL: gtk3;
Locale: en-CA (en_CA.UTF-8); UI-Language: en-US
Calc: threaded

Thanks,

Julian