You should be able to delete all of Configurations2/..., Thumbnails/thumbnail.png, and manifest.rdf without any harm whatsoever, so long as the related <manifest:file-entry> elements are deleted from META-INF/manifest.xml.
You should probably *not* keep the settings.xml if you are creating a different content.xml file (just in case).
You might check on consistency of version attribute occurrences and their values. For ODF 1.2 documents, it is expected that there will be a consistent use of "1.2" in a variety of places. If there are any missing version attributes or ones with conflicting values of "1.0" or "1.1", that might be a problem as well.
This is a bit trickier. What version of ODF are you specifying in your "template" and the subsequent manipulations?
It could be none of these that are derailing LO. It could be some sort of problem being caught in the resolution of styles, or some problem where automatic styles are involved.
SOMETHING ELSE TO TRY
When LO says the document is corrupted, do you have an option to attempt "recovery" or "repair"? When you exercise that option, can you save the result and reopen *that* successfully in LO ? I think you have done this according to your other report.
If that works, you then need to figure out what it is that is different in the repaired one and the one that was declared corrupt. Look at the manifest and the files that are present, and in the root element opening tags for styles.xml and content.xml. (Notice the office:version attributes and any manifest:version attributes as well.) Check to see whether automatic styles were added to content.xml where there are none (?) for your "corrupted" document.
- Dennis